A New Series of Organoboranes. IV. The Participation of the 1,2-Dicarbaclovododecaborane(12) Nucleus in Some Novel Heteratomic Ring Systems
A New Series of Organoboranes. IV. The Participation of the 1,2-Dicarbaclovododecaborane(12) Nucleus in Some Novel Heteratomic Ring Systems
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有机硼烷新系列。
DOI：
10.1021/ic50010a005
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发表时间：
1963
影响因子：
4.6
通讯作者：
T. L. Heying
中科院分区：
文献类型：
--
作者：
S. Papetti;T. L. Heying
翻译后摘要：各种chlorosilylcarborane（Carborane用于代替正式名称11，12-dicarbadodeca硼烷）衍生物的制备。在随后与胺或水的反应中，显示出形成五元二硅氮烷和二硅氧烷环的显著倾向。在与二硫代碳硼烷的反应中，形成了新的二硅杂环己烷类似物。
Abstract : Various chlorosilylcarborane (Carborane is used in place of the formal name 11,12-dicarbadodeca borane) derivatives were prepared. In subsequent reactions with amines or water a marked pro pensity for the formation of five membered disila azane and disila oxane rings was exhibited. In reactions with dilithiocarborane, novel disilacyclohexane analogs were formed.