The 193-nm photodissociation of cyclobutanone: dynamics of the C2 and C3 channels
The 193-nm photodissociation of cyclobutanone: dynamics of the C2 and C3 channels
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DOI：
10.1021/j100370a055
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发表时间：
1990-04
期刊：
影响因子：
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通讯作者：
K. Trentelman;D. Moss;S. Kable;P. Houston
中科院分区：
文献类型：
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作者：
K. Trentelman;D. Moss;S. Kable;P. Houston
结论本文报道的实验是为了获得有关氟氯胺的光谱信息，并研究由它们光解产生各种NX 2，NXY和NX片段的可能性。NFC 12和NF 2C 1的紫外吸收光谱表明，在200-400 nm范围内可达到解离态，这些状态通过低温基质隔离物种的光解来探测。从数据中可以明显看出，
Conclusion The experiments reported here were carried out to obtain information concerning the spectroscopy of the fluorochloroamines and to examine the possibility of producing various NX2, NXY, and NX fragments from them photolytically. The UV absorption spectra of NFC12 and NF2C1 indicatethat dissociative states are accessible in the 200-400-nm range, andthese states were probed via photolysis of the low-temperature matrix-isolated species. It is apparent from the data that the excited states produced in