Highly porous, homochiral metal-organic frameworks: Solvent-exchange-induced single-crystal to single-crystal transformations
Highly porous, homochiral metal-organic frameworks: Solvent-exchange-induced single-crystal to single-crystal transformations
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DOI：
10.1002/anie.200462711
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发表时间：
2005-01-01
影响因子：
16.6
通讯作者：
Lin, WB
中科院分区：
文献类型：
--
作者：
Wu, CD;Lin, WB
变化和变化：当暴露于溶剂蒸气或空气中时，高度多孔、同手性金属有机框架（MOF）会经历可逆的单晶到单晶、单晶到非晶到单晶的结构转变。这些结果表明，真正的多相不对称催化剂可以由纯手性 MOF 构建。（提供化学方程式）。© 2005 Wiley-VCH Verlag GmbH & Co. KGaA。
Change and change about: Highly porous, homochiral metal-organic frameworks (MOFs) undergo reversible single-crystal to single-crystal and single-crystal to amorphous to single-crystal structural transformations when exposed to solvent vapors or air. These results suggest that true heterogeneous asymmetric catalysts can be built from homochiral MOFs.(Chemical Equation Presented).© 2005 Wiley-VCH Verlag GmbH & Co. KGaA.