Potassium fluoride-induced 1,4-elimination of o-[(trimethylsilyl)methyl]benzyl acetates:: A versatile generation of o-quinodimethanes
Potassium fluoride-induced 1,4-elimination of o-[(trimethylsilyl)methyl]benzyl acetates:: A versatile generation of o-quinodimethanes
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DOI：
10.1246/cl.2005.728
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发表时间：
2005-05-05
影响因子：
1.6
通讯作者：
Shige, T
中科院分区：
文献类型：
--
作者：
Kuwano, R;Shige, T
以邻[（三甲基硅基）甲基]乙酸苄酯和氟化钾为原料，合成了邻醌二甲烷中间体。邻醌二甲烷与缺电子烯烃反应，得到[4+2]环加合物，即四氢萘。
o-Quinodimethane interemediate was generated from o-[(trimethylsilyl)methyl]benzyl acetate with potassium fluoride. The o-quinodimethane in hand reacted with electron-deficient olefins, affording [4+2] cycloadducts, tetrahydronaphthalenes.