A very large metallosupramolecular capsule with cube-like 43 topology assembled from twelve Cu(II) centers and eight tri-bidentate tri-anionic ligands derived from 2,4,6-triphenylazo-1,3,5-trihydroxybenzene
A very large metallosupramolecular capsule with cube-like 43 topology assembled from twelve Cu(II) centers and eight tri-bidentate tri-anionic ligands derived from 2,4,6-triphenylazo-1,3,5-trihydroxybenzene
复制标题
DOI：
10.1021/ja990016t
复制
发表时间：
1999-04-14
影响因子：
15
通讯作者：
Robson, R
中科院分区：
文献类型：
--
作者：
Abrahams, BF;Egan, SJ;Robson, R
马丁B。霍金（维多利亚大学）。学术出版社：纽约。1998. 24 + 777页一百二十五块ISBN 0-12-350810-X。这本书的目标是提供“工业和环境化学领域的统一处理”，目标受众包括应用化学，工程和环境计划的高年级学生，以及在这些领域雇用的专业人员和顾问。这项工作的基本理念是，工艺化学和排放信息的综合介绍为理解排放的性质和来源提供了一个背景。它还提供了一个机会，以确定工艺变化，以减少现有设施的环境影响，而不是增加“管道末端”处理解决方案。任何一本范围如此之大的单卷书肯定会让一些读者失望，因为缺乏关于他们感兴趣的主题的信息。考虑到这一限制，可以说，这本书做了一个合理的工作，提出了一个概述的主要化学工业的利益在加拿大和美国。实例包括钠盐和钾盐、硫酸、硝酸和磷酸、氨、金属（铝、铜、铁和钢）、纸浆和纸、石油生产、精炼和石化产品以及聚合物。第一章（背景和技术方面）给出了一些化学工程核心材料，即规模经济，反应器类型，转化率和产率，以及仪器仪表的非常简要的概述。它可能是重要的和感兴趣的学生在应用化学，但将在很大程度上已经知道的从业者。这里不讨论分离技术，尽管乙醇和原油的蒸馏在后面分别涉及发酵和精炼的章节中进行了介绍。在将来的版本中，对分离进行更广泛的讨论可能是值得的，因为不完全的分离常常是化学加工中产生污染的一个来源。
Martin B. Hocking (University of Victoria). Academic Press: New York. 1998. xxiv+ 777 pp. $125. ISBN 0-12-350810-X. The stated objectives of this book are to provide a “unified treatment of the fields of industrial and environmental chemistry”, with a target audience including senior students in applied chemistry, engineering, and environmental programs, as well as professionals and consultants employed in these areas. The underlying philosophy in this work is that a combined presentation of the process chemistry and emissions information provides a context for understanding the nature and sources of emissions. It also provides an opportunity for identifying process changes for reducing environmental impact in existing facilities, rather than adding on “end-of-pipe” treatment solutions. Any single volume book with such a large scope is bound to disappoint some readers, due to a lack of information on their topic of interest. With that limitation in mind, it can be said that the book does a reasonable job presenting an overview of the primary chemicals industries of interest in Canada and the United States. Examples include sodium and potassium salts, sulfuric, nitric and phosphoric acid, ammonia, metals (aluminum, copper, iron, and steel), pulp and paper, petroleum production, refining and petrochemicals, and polymers. The first chapter (Background and Technical Aspects) gives a very brief overview of some chemical engineering core material, ie, economy of scale, reactor types, conversion and yield, and instrumentation. It is perhaps of importance and interest to students in applied chemistry but will be largely known already to practitioners. No separation technologies are discussed here, although distillation of ethanol and crude oil is covered in later chapters dealing with fermentation and refining, respectively. It might be worthwhile including some more extensive discussion on separations in future editions, since incomplete separations are frequently a source of pollution generation in chemical processing.