Donor-substituted peralkynylated "radiaannulenes": novel all-carbon macrocycles with an intense intramolecular charge-transfer.
Donor-substituted peralkynylated "radiaannulenes": novel all-carbon macrocycles with an intense intramolecular charge-transfer.
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供体取代的全炔基化“radiaannulenes”：具有强烈分子内电荷转移的新型全碳大环化合物。
作者：
F. Mitzel;C. Boudon;J. Gisselbrecht;P. Seiler;M. Gross;F. Diederich
一类新的平面，高度共轭的全碳大环，我们命名为“radiaannulenes”，已准备基于炔支架使用四乙炔基乙烯（TEE）积木，这些结构是强大的电子受体，并在外围取代后，与电子供体N，N-二烷基苯胺基，显示强烈的分子内电荷转移。
A novel class of planar, highly conjugated all-carbon macrocycles, which we christened "radiaannulenes", have been prepared based on acetylenic scaffolding using tetraethynylethene (TEE) building blocks; these structures are powerful electron acceptors and, upon peripheral substitution with electron-donating N,N-dialkylanilino groups, display intense intramolecular charge-transfer.