Nickel-Catalyzed Reaction of Thioisatins and Alkynes: A Facile Synthesis of Thiochromones
Nickel-Catalyzed Reaction of Thioisatins and Alkynes: A Facile Synthesis of Thiochromones
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DOI：
10.1021/ol5026102
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发表时间：
2014-11-07
期刊：
影响因子：
5.2
通讯作者：
Matsubara, Seijiro
中科院分区：
文献类型：
--
作者：
Inami, Tasuku;Kurahashi, Takuya;Matsubara, Seijiro
采用镍催化易得的硫代嘌呤与炔烃进行脱羰环加成，制备了一种合成硫代色素的新方法。该反应在非常温和的条件下进行，具有相当高的官能团相容性。
A new synthetic method for thiochromones was developed by using nickel-catalyzed decarbonylative cycloaddition of readily available thioisatins with alkynes. This reaction proceeded under very mild conditions and has quite high functional group compatibility.