Nickel-catalyzed hydrogen isotope exchange
Nickel-catalyzed hydrogen isotope exchange
复制标题
DOI：
10.1002/jlcr.1822
复制
发表时间：
2010-09-15
影响因子：
1.8
通讯作者：
Heys, J. Richard
中科院分区：
文献类型：
--
作者：
Heys, J. Richard
各种形式的金属镍可用于同位素水或同位素氢气来源的各种化合物的催化交换标记。对金属在简单测试化合物中的活性进行了大量的调查工作，为选择或开发更复杂物质的标记条件提供了有用的信息。此外，Raney镍已被证明对碳水化合物的标记特别有用，对于这些碳水化合物，收集的经验数据足以用于新糖苷的有限预测目的。
Nickel metal in various forms is useful for the catalytic exchange labeling of a wide range of compounds from isotopic water or isotopic hydrogen gas sources. Substantial investigative work has been done on the metal's activities in simple test compounds, providing information useful for selecting or developing conditions for labeling of more complex substances. In addition, Raney nickel has been shown to be particularly useful for labeling of carbohydrates, for which the assembled empirical data are sufficient for limited predictive purposes in new glycosides.