Tracking coherent population transfer and thermal population relaxation in condensed system by broad-band transient grating spectroscopy

Tracking coherent population transfer and thermal population relaxation in condensed system by broad-band transient grating spectroscopy
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通过宽带瞬态光栅光谱跟踪凝聚系统中的相干布居转移和热布居弛豫

DOI:
10.1088/1361-6455/aab1aa
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发表时间:
2018-03
期刊:
Journal of Physics B: Atomic, Molecular and Optical Physics
影响因子:
--
通讯作者:
Yang Yanqiang
Yang Yanqiang
中科院分区:
其他
文献类型:
--
作者:
Zhang Wei;Liu Xiaosong;Wu Honglin;Song Yunfei;Liu Weilong;Yang Yanqiang

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Broad-band transient grating (BB-TG) spectroscopy was proposed to track both coherent population transfer (CPT) and thermal population relaxation processes in a condensed system of solvated molecules in solution (Rhodamine101 in methanol). A broad band around 1500 cm−1 and a relative narrow band near 2900 cm−1 emerge in TG and transient absorption contour plots when pump and probe pulses overlap in the sample. The experimental results matched well with the vibrational modes of Rhodamine101 that were obtained by theoretical calculation. In addition, it was found that the population of CPT particles can be evaluated quantitatively through the intensity of the TG signal.
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