Chiron approach for the synthesis of (1S,2R,5R,7S)-2-hydroxy-exo-brevicomin
Chiron approach for the synthesis of (1S,2R,5R,7S)-2-hydroxy-exo-brevicomin
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DOI：
10.1016/j.tetasy.2006.02.020
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发表时间：
2006-03-06
影响因子：
--
通讯作者：
Rao, BV
中科院分区：
文献类型：
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作者：
Gautam, D;Kumar, DN;Rao, BV
(1S,2R,5R,7S)-2-Hydroxy-exo-brevicomin ent-1 was synthesized from 1,2;5,6-di-O-isopropylidene-(D)-glucose in seven steps. The key reaction in our synthesis is the formation of bicyclic ketal 7 under acid mediated acetal exchange of a 1,2-acetonide Of D-glucose derivative 6. (c) 2006 Elsevier Ltd. All rights reserved.
