Catalyst-Controlled Highly Selective Coupling and Oxygenation of Olefins: A Direct Approach to Alcohols, Ketones, and Diketones

Catalyst-Controlled Highly Selective Coupling and Oxygenation of Olefins: A Direct Approach to Alcohols, Ketones, and Diketones
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催化剂控制的烯烃高选择性偶联和氧化:直接制备醇、酮和二酮的方法

DOI:
10.1002/anie.201303917
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发表时间:
2013-09-09
影响因子:
16.6
通讯作者:
Jiao, Ning
Jiao, Ning
中科院分区:
化学1区
文献类型:
--
作者:
Su, Yijin;Sun, Xiang;Jiao, Ning

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The article focuses on the study regarding the catalysis of highly selective coupling and oxygenation of olefins. The hypothesis of the study explore the tandem radical addition/oxygenation sequence which begun by examining the reactions of phenyl hydrazine (1) with the presence of styrene (2a). The study argued that the selectivity of the synthesis of several compounds such as alcohols, ketones, and diketones is switched by the selection of different types of catalysts.