A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates
A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates
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DOI：
10.1039/b914919h
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Ferey, Gerard
中科院分区：
文献类型：
--
作者：
Guillerm, Vincent;Gross, Silvia;Ferey, Gerard
甲基丙烯酸锆氧簇合物Zr 6 O 4（OH）（4）（OMc）（12）（OMc = CH 2 = CH（CH 3）COO）的单羧酸配体与二羧酸（反式、反式粘康酸和对苯二甲酸）的交换导致呈现UiO-66结构的多孔二羧酸锆;温和的反应条件允许控制其粒度。
The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)(4)(OMc)(12) (OMc = CH2 = CH(CH3)COO) with dicarboxylic acids (trans, trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.