Electrochemistry of Oil-Water Interfaces

Electrochemistry of Oil-Water Interfaces
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油水界面电化学

DOI:
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发表时间:
1984
期刊:
影响因子:
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通讯作者:
A. Watanabe
A. Watanabe
中科院分区:
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文献类型:
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作者:
A. Watanabe

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当两相彼此接触时,中性组分j对两相中的一相比另一相具有更强的亲和力。例如,油酸在油中比在水中更易溶。然而,随着拥挤程度的增加,长链酸将发现更难以驻留在前相中。这种趋势用化学势来表示;组分j显示出从较高化学势的相移动到较低化学势的相的趋势。
When two phases are in contact with each other, a neutral component j has a stronger affinity to one of the two phases than the other. For instance, oleic acid is more soluble in oil than in water. However, with increased crowding the long-chain acid will find it more difficult to reside in the former phase. This tendency is expressed by means of the chemical potential; a component j shows the tendency to move from a phase of higher chemical potential to that of the lower one.