Thermo-electric method for nearly complete oxidization of highly iron-doped lithium niobate crystals

Thermo-electric method for nearly complete oxidization of highly iron-doped lithium niobate crystals
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热电法几乎完全氧化高铁掺杂铌酸锂晶体

DOI:
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发表时间:
2005
期刊:
影响因子:
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通讯作者:
K. Buse
K. Buse
中科院分区:
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文献类型:
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作者:
M. Falk;K. Buse

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提出了一种新方法,在外部施加电场的情况下,利用 700°C 退火,使掺有大量氧化铁(0.05–3 wt. % Fe2O3)的铌酸锂晶体 (LiNbO3) 几乎完全氧化。处理导致Fe2+和Fe3+离子的浓度比小于2×10-3。 LiNbO3 中铁的强氧化作用降低了光折变效应,因此对于非线性光学应用特别感兴趣。
A new method is presented, allowing the nearly complete oxidization of lithium niobate crystals (LiNbO3), doped with large amounts of iron oxide (0.05–3 wt. % Fe2O3) utilizing annealing at 700 °C in the presence of externally applied electric fields. The treatment results in a concentration ratio of Fe2+ and Fe3+ ions of less than 2×10-3. Strong oxidization of iron in LiNbO3 reduces the photorefractive effect and is therefore of particular interest for nonlinear-optical applications.