The first ionothermal synthesis of a 3D ferroelectric metal-organic framework with colossal dielectric constant.
The first ionothermal synthesis of a 3D ferroelectric metal-organic framework with colossal dielectric constant.
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DOI：
10.1039/c0cc04890a
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发表时间：
2011-03
影响因子：
4.9
通讯作者：
W. Ji;Q. Zhai;Shu’ni Li;Yucheng Jiang;Mancheng Hu
中科院分区：
文献类型：
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作者：
W. Ji;Q. Zhai;Shu’ni Li;Yucheng Jiang;Mancheng Hu
以溴化1-乙基-3-甲基咪唑（[EMI]Br）为溶剂和结构导向剂，在离子交换条件下得到了一种新型的3D（4，6）-连接拓扑结构，该结构呈现出非中心对称的极性堆积排列，显示出有趣的铁电性质.
A novel 3D (4,6)-connected topological architecture, obtained under ionothermal conditions by using 1-ethyl-3-methyl imidazolium bromide ([EMI]Br) as solvent and structure-directing agent, presents a non-centrosymmetric polar packing arrangement showing an interesting ferroelectric property.