Understanding the behavior of N-tosyl and N-2-pyridylsulfonyl Imines in CuII-Catalyzed aza-friedel-crafts reactions
Understanding the behavior of N-tosyl and N-2-pyridylsulfonyl Imines in CuII-Catalyzed aza-friedel-crafts reactions
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DOI：
10.1021/jo800986g
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发表时间：
2008-08-15
影响因子：
3.6
通讯作者：
Carretero, Juan C.
中科院分区：
文献类型：
--
作者：
Alonso, Ines;Esquivias, Jorge;Carretero, Juan C.
描述了N-甲苯磺酰亚胺和N-（2-吡啶基）磺酰亚胺在Cu-II催化的AFCR中的不同行为。DFT理论计算的铜原子的两种类型的基板的协调模式允许理解这种不同的反应性。
[GRAPHICS]The different behavior of N-tosyl imines and N-(2-pyridyl)sulfonyl imines in Cu-II-catalyzed AFCR is described. DFT theoretical calculations on the mode of coordination of the copper atom to both types of substrates allow understanding this different reactivity.