Catalysis by a synthetic receptor sealed at one end and functionalized at the other.
Catalysis by a synthetic receptor sealed at one end and functionalized at the other.
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DOI：
10.1021/ja045167x
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发表时间：
2004-11
影响因子：
15
通讯作者：
Sébastien Richeter;J. Rebek
中科院分区：
文献类型：
--
作者：
Sébastien Richeter;J. Rebek
A deep cavitand bearing a zinc (II) salen wall catalyzes the hydrolysis of para-nitrophenylcholine carbonate. The closed end of the cavitand properly positions the carbonyl function of the substrate for activation by the metal center. Substrate specificity for acetylcholine derivatives results from simultaneous cation-pi interactions and a C=O- - -Zn coordination bond.
