Transition Metal-Catalyzed C—H Trifluoromethylation

Transition Metal-Catalyzed C—H Trifluoromethylation
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DOI:
10.6023/a12040135
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发表时间:
2012-08
影响因子:
2.5
通讯作者:
Pan Fei;Zhangjie Shi
Pan Fei;Zhangjie Shi
中科院分区:
化学3区
文献类型:
--
作者:
Pan Fei;Zhangjie Shi

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近年来,过渡金属催化的C-H三氟甲基化反应得到了很好的发展,主要集中在末端炔C(sp)- H、芳香和杂环C(sp 2)- H和烯丙基C(sp 3)- H三氟甲基化反应。本文简要综述了该领域的最新进展,各类反应的特点,以及面临的挑战和未来的发展方向。
In recent years, transition metal-catalyzed C — H trifluoromethylation has been well developed, which is mainly focused on the terminal alkyne C(sp) — H, aromatic and heterocyclic C(sp 2 ) — H and allylic C(sp 3 ) — H trifluoromethylation. This paper briefly overviews the latest developments in this field, the characteristics of various types of reaction, as well as the facing challenges and future direction.