Hydrolysis Studies of Phosphodichloridate and Thiophosphodichloridate Ions
Hydrolysis Studies of Phosphodichloridate and Thiophosphodichloridate Ions
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DOI：
10.1021/jo300808m
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发表时间：
2012-07-06
影响因子：
3.6
通讯作者：
Hodgson, David R. W.
中科院分区：
文献类型：
--
作者：
Delley, Richard J.;O'Donoghue, AnnMarie C.;Hodgson, David R. W.
本文报道了水溶液中二氯磷酸盐和硫代二氯酸根离子的pH-k(OBS)曲线。这两个物种都表现出广泛的pH-k(Obs)高原，并延伸到高PHS。
We report the pH-k(obs), profiles for the hydrolyses of phosphodichloridate and thiophosphodichloridate ions in aqueous solutions. Both species show broad pH-k(obs) plateaus that extend to high pHs.