CIRCULAR-DICHROISM STUDY ON THE DIASTEREOSELECTIVE SELF-ASSEMBLY OF BACTERIOCHLOROPHYLL C(S)

CIRCULAR-DICHROISM STUDY ON THE DIASTEREOSELECTIVE SELF-ASSEMBLY OF BACTERIOCHLOROPHYLL C(S)
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DOI:
10.1016/0022-2860(95)08739-i
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发表时间:
1995-04-01
影响因子:
3.8
通讯作者:
SCHAFFNER, K
SCHAFFNER, K
中科院分区:
化学2区
文献类型:
--
作者:
BALABAN, TS;HOLZWARTH, AR;SCHAFFNER, K

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自组装细菌叶绿素c(s)(BChlc(s))聚集体的圆二色性(CD)光谱显示出对溶剂、浓度和3(1)-羟基的立体化学的显著依赖性。在正己烷中,由于纳米结构聚集体的形成,获得了PSI型CD。
Circular dichroism (CD) spectra of self-assembled bacteriochlorophyll c(s) (BChl c(s)) aggregates show a pronounced dependency on the solvent, the concentration and on the stereochemistry of the 3(1)-hydroxy groups. In n-hexane a psi-type CD is obtained due to the formation of nanostructural aggregates.