Synthesis and characterization of an iron(II) η2-hydrazine complex
Synthesis and characterization of an iron(II) η2-hydrazine complex
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DOI：
10.1021/ic702007r
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发表时间：
2007-12-10
影响因子：
4.6
通讯作者：
Tyler, David R.
中科院分区：
文献类型：
--
作者：
Crossland, Justin L.;Zakharov, Lev N.;Tyler, David R.
合成了铁膦配合物顺-[Fe(DMeOPrPE)(2)(eta(2)-N2H4)][BPh4](2) {DMeOPrPE = 1,2-双[双(甲氧基丙基)膦基]乙烷}并进行了结构表征。该结构表现出肼与铁的第一个eta(2)配位，这可能与固氮酶周转过程中捕获的中间体有关。 I 与酸的反应导致通过歧化反应形成氨。
The iron phosphine complex cis-[Fe(DMeOPrPE)(2)(eta(2)-N2H4)][BPh4](2) {DMeOPrPE = 1,2-bis[bis(methoxypropyl)phosphino]ethane} was synthesized and structurally characterized. The structure exhibits the first eta(2) coordination of hydrazine to iron, which may be relevant to intermediates trapped during nitrogenase turnover. The reaction of I with acid results in the formation of ammonia via a disproportionation reaction.