Nasicon formation by chemical polymerization
Nasicon formation by chemical polymerization
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DOI：
10.1016/0025-5408(83)90019-3
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发表时间：
1983-10
影响因子：
5.4
通讯作者：
B. E. Yoldas;I. Lloyd
中科院分区：
文献类型：
--
作者：
B. E. Yoldas;I. Lloyd
提出了一种允许在室温下形成具有菱面体结构的NASICON化合物的化学聚合方法。这种方法避开了与这些材料相关的潜在破坏性的单斜方相变。这种化学聚合方法也被发现消除了在这类固体电解质中用传统方法形成时一贯存在的“游离氧化锆”的出现。
A chemical polymerization method which allows the formation of NASICON compounds having rhombohedral structure at room temperature is presented. This method circumvents the potentially destructive monoclinic-rhombohedral phase transformation associated with these materials. This chemical polymerization method is also found to eliminate the occurrence of “free-zirconia” which is consistently encountered in this class of solid electrolytes when they are formed by tradiational methods.