Cobalt catalyst with a proton-responsive ligand for water oxidation.
Cobalt catalyst with a proton-responsive ligand for water oxidation.
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DOI：
10.1002/chem.201405020
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发表时间：
2015-02
期刊：
影响因子：
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通讯作者：
Inke Siewert;J. Gałęzowska
中科院分区：
文献类型：
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作者：
Inke Siewert;J. Gałęzowska
本文报道了一种新的单核钴配合物的合成、热化学数据和催化反应性，该配合物在配体球中有四个NH质子。氧化活性金属离子和NH单元的结合使质子和电子转移步骤耦合，我们在电催化水氧化中利用了这一步骤。
Herein, we report the synthesis, the thermochemical data, and the catalytic reactivity of a new mononuclear cobalt complex, which has four NH protons in the ligand sphere. The combination of the redox-active metal ion and NH units enabled the coupling of proton and electron-transfer steps, which we exploited in the electrocatalytic water oxidation.