Platinum chloride deposition into C60 nanotubes
Platinum chloride deposition into C60 nanotubes
复制标题
DOI：
10.1016/j.matlet.2007.05.069
复制
发表时间：
2008-02-15
影响因子：
3
通讯作者：
Ringor, Cherry
中科院分区：
文献类型：
--
作者：
Miyazawa, Kun'ichi;Ringor, Cherry
使用透射电子显微镜 (TEM) 研究了氯化铂 (PtCl4) 在 C-60 纳米管 (C60NT) 中的沉积。所制备的 C60NT 显示拉曼图谱，表明 C-60 分子和 C-60 二聚体的一维聚合结构的形成。然而，在室温下干燥的 C60NT 转变为范德华聚合物。通过将 PtCl4 的异丙醇 (IPA) 溶液渗透到真空干燥的 C60NT 中，成功地进行了 PtCl4 的沉积。建议C60NTs可用作各种化学物质的载体，包括用于从液体废物中回收Pt。 (C) 2007 Elsevier B.V. 保留所有权利。
Deposition of platinum chloride (PtCl4) into C-60 nanotubes (C60NTs) was investigated using transmission electron rnicroscopy (TEM). The as-prepared C60NTs showed a Raman profile indicating the formation of one-dirnensionally polymerized structure of C-60 molecules and C-60 dimers. However, the C60NTs dried at room temperature turned to van der Waals polymers. The deposition of PtCl4 was successfully performed by infiltrating an isopropyl alcohol (IPA) solution of PtCl4 into the C60NTs dried in vacuum. It is suggested that the C60NTs can be used as carriers for various chemical substances, including the use to recover Pt from liquid wastes. (C) 2007 Elsevier B.V. All rights reserved.