New molecular switch architectures

New molecular switch architectures
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DOI:
10.1073/pnas.1714499115
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发表时间:
2018-09-18
影响因子:
11.1
通讯作者:
Aprahamian, Ivan
Aprahamian, Ivan
中科院分区:
综合性期刊1区
文献类型:
--
作者:
Harris, Jared D.;Moran, Mark J.;Aprahamian, Ivan

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在本文中,我们详细介绍了最近开发的分子开关架构,以及这些新系统如何有助于实现新的功能和人工分子机器的进步。本文总结了化学和光致开关和电机方面的进展并将其置于背景中,以便读者能够了解过去十年中出现的新颖工具。这些系统中的许多系统提供了与常用开关相比的明显优势,包括改善的保真度、可寻址性和鲁棒性。因此,本文作为一个起点,研究人员寻求新的开关图案的特定应用,或解决目前可用的系统的局限性。
In this paper we elaborate on recently developed molecular switch architectures and how these new systems can help with the realization of new functions and advancement of artificial molecular machines. Progress in chemically and photoinduced switches and motors is summarized and contextualized such that the reader may gain an appreciation for the novel tools that have come about in the past decade. Many of these systems offer distinct advantages over commonly employed switches, including improved fidelity, addressability, and robustness. Thus, this paper serves as a jumping-off point for researchers seeking new switching motifs for specific applications, or ones that address the limitations of presently available systems.