Synthesis and structural characterisation of a magnesium bisenolate:: a tetrameric (Mg2O2)2 chain terminated by solvating ketone

Synthesis and structural characterisation of a magnesium bisenolate:: a tetrameric (Mg2O2)2 chain terminated by solvating ketone
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DOI:
10.1039/b002892o
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发表时间:
2000-01-01
影响因子:
4.9
通讯作者:
Teat, SJ
Teat, SJ
中科院分区:
化学2区
文献类型:
--
作者:
Allan, JF;Henderson, KW;Teat, SJ

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一个反应性的镁烯醇中间体已被确定含有显着的组合物的四种金属,8烯醇化物(六个桥接和两个末端结合)和两个unenolised酮,并讨论了其在羟醛加成反应的影响。
A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.