Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations
Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations
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DOI：
10.1016/0040-4039(96)00823-4
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发表时间：
1996-06-10
影响因子：
1.8
通讯作者：
Fall, MJ
中科院分区：
文献类型：
--
作者：
Davies, HML;Bruzinski, PR;Fall, MJ
铑（II）（S）-N-（芳基磺酰基）脯氨酸盐催化的含有甲基酯和乙烯基或苯基的重氮烷烃在烯烃存在下的分解导致高度非对映选择性和对映选择性的环丙烷化。(C)1996年爱思唯尔科学有限公司
Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed decomposition of diazoalkanes containing a methyl ester and either a vinyl or a phenyl group in the presence of alkenes results in highly diastereoselective and enantioselective cyclopropanations. (C) 1996 Elsevier Science Ltd