The History of Ozone. Part III
The History of Ozone. Part III
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臭氧的历史。
DOI：
10.1002/hlca.200390111
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发表时间：
2003
影响因子：
1.8
通讯作者：
M. Rubin
中科院分区：
文献类型：
--
作者：
M. Rubin
臭氧引入有机化学是由于c.d.的工作。在1903-1916年期间，他首先在柏林，但主要是在基尔。他建立了臭氧分解的实验程序，证明了不饱和化合物与臭氧反应的普遍性，并表明臭氧可用于合成各种敏感化合物。对于有机化学的未来发展最重要的是，他确立了臭氧分解可以成为确定有机化合物结构的重要工具。他还开始研究臭氧与烯烃反应的机理，大约四十年后，在克里吉臭氧分解机制中达到高潮。
The introduction of ozone into organic chemistry is due to the work of C. D. Harries, first in Berlin but mainly in Kiel, during the period 1903–1916. He established experimental procedures for ozonolysis, demonstrated the generality of the reaction of unsaturated compounds with ozone, and showed that ozone could be used for the synthesis of a variety of sensitive compounds. Most important for the future development of organic chemistry, he established that ozonolysis could be an important tool for determining the structures of organic compounds. He also initiated investigations into the mechanism of ozone reactions with alkenes, which culminated about forty years later in the Criegee mechanism for ozonolysis.