c‐TiS2, a New Modification of Titanium Disulfide with Cubic Structure
c‐TiS2, a New Modification of Titanium Disulfide with Cubic Structure
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c-TiS2，具有立方结构的二硫化钛的新变体
DOI：
10.1002/anie.198500671
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发表时间：
1985
期刊：
影响因子：
--
通讯作者：
A. Payer
中科院分区：
文献类型：
--
作者：
R. Schöllhorn;A. Payer
TiS2 的亚稳态改性通过室温下的拓扑固相反应制备，其中 CuTi2S4 工作电极在非质子铜（I）电解质中进行阳极氧化。根据X射线粉末数据，可以确定新相属于极少见的AB2结构类型。这种立方 TiS2 作为二次电池中可逆电极的材料尤其令人感兴趣。它比六方TiS2（层状晶格）具有优势。
A metastable modification of TiS2has been prepared by a topotactic solid‐state reactionat room temperature in which CuTi2S4working electrodes were anodically oxidized in aprotic copper(I) electrolytes. On the basis of X‐ray powder data, it can be determined that the new phase belongs to a very seldom AB2structural type. This cubic TiS2is of interest, inter alia, as a material for reversible electrodes in secondary batteries. It has advantages over hexagonal TiS2(layer lattice).