ALMOST PERFECT ENANTIO-DIFFERENTIATING HYDROGENATION OF METHYL 3-CYCLOPROPYL-3-OXOPROPANOATE OVER TARTARIC ACID MODIFIED RANEY NICKEL CATALYST
ALMOST PERFECT ENANTIO-DIFFERENTIATING HYDROGENATION OF METHYL 3-CYCLOPROPYL-3-OXOPROPANOATE OVER TARTARIC ACID MODIFIED RANEY NICKEL CATALYST
复制标题
酒石酸改性雷尼镍催化剂上 3-环丙基-3-氧代丙酸甲酯几乎完美的对映异构化加氢反应
DOI：
10.1246/cl.1997.859
复制
发表时间：
1997
影响因子：
1.6
通讯作者：
A. Tai
中科院分区：
文献类型：
--
作者：
S. Nakagawa;T. Sugimura;A. Tai
采用不对称改性多相催化剂，实现了近乎完美的对映体分化加氢。将3-环丙基-3-氧丙酸甲酯在酒石酸修饰的兰尼镍上加氢得到光学纯度超过98%的3-环丙基-3-羟基丙酸甲酯。
Almost perfect enantio-differentiating hydrogenation was achieved by asymmetrically modified heterogeneous catalyst. The hydrogenation of methyl 3-cyclopropyl-3-oxopropanoate over tartaric acid modified Raney nickel gave methyl 3-cyclopropyl-3-hydroxypropanoate in more than 98% of optical purity.