XAFS Analysis of Ti and Ni Dissolution from Pure Ti, Ni-Ti Alloy, and SUS304 in Soft Tissues

XAFS Analysis of Ti and Ni Dissolution from Pure Ti, Ni-Ti Alloy, and SUS304 in Soft Tissues
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DOI:
10.1246/cl.2008.958
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发表时间:
2008-09-05
期刊:
影响因子:
1.6
通讯作者:
Watari, Fumio
Watari, Fumio
中科院分区:
化学4区
文献类型:
--
作者:
Uo, Motohiro;Asakura, Kiyotaka;Watari, Fumio

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将Ti (Ni-Ti合金)和不锈钢(SUS304)植入大鼠软组织6个月。采用荧光x射线吸收线结构(XAFS)分析了金属植入体周围组织中所含成分元素的化学状态。在周围组织中检测到氧化钛和镍水合物,这是由钛和镍的侵蚀引起的。组织中Ti和Ni的浓度分别为1-3 ppm和300 ppm。从而成功地确定了这些实用金属材料在体内的溶解条件和浓度。
Ti, a Ni-Ti alloy, and stainless steel (SUS304) were implanted in rat soft tissues for 6 months. The chemical states of the component elements contained in the tissues surrounding those metallic implants were analyzed by fluorescence X-ray absorption line structure (XAFS). Titanium oxide and a nickel aquo complex, which Would be Caused by the erosion of Ti and Ni, were detected in the Surrounding tissues. The concentrations of Ti and Ni in the tissues were 1-3 and 300 ppm, respectively. Thus, the dissolved conditions and concentrations of those practical metallic materials in vivo were successfully confirmed.