Sunlight-Driven Synthesis of Triarylethylenes (TAEs) via Metal-Free Mizoroki-Heck-Type Coupling
Sunlight-Driven Synthesis of Triarylethylenes (TAEs) via Metal-Free Mizoroki-Heck-Type Coupling
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DOI：
10.1002/ejoc.201800883
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发表时间：
2018-08
影响因子：
2.8
通讯作者：
L. Onuigbo;Carlotta Raviola;Andrea Di Fonzo;S. Protti;M. Fagnoni
中科院分区：
文献类型：
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作者：
L. Onuigbo;Carlotta Raviola;Andrea Di Fonzo;S. Protti;M. Fagnoni
以芳基偶氮砜为底物，在1，1-二芳基乙烯存在下，发展了一种制备取代三芳基乙烯（TAE）的方法。该过程在不存在任何（光）催化剂的情况下在反应混合物暴露于（模拟）阳光时有效地发生。
A protocol for the preparation of substituted triarylethylenes (TAEs) was developed by using arylazo sulfones as substrates in the presence of 1,1‐diarylethylenes. The process took place efficiently in the absence of any (photo)catalyst upon exposure of the reaction mixture to (simulated) sunlight.