Magnesium alcoholates as precursors for magnesia
Magnesium alcoholates as precursors for magnesia
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DOI：
10.1039/jm9950500589
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发表时间：
1995
影响因子：
--
通讯作者：
H. Thoms;M. Epple;H. Viebrock;A. Reller
中科院分区：
文献类型：
--
作者：
H. Thoms;M. Epple;H. Viebrock;A. Reller
报道了六种不同的醇镁化合物的合成、结构和热行为。通过醇盐分解获得的氧化镁显示出不同的颗粒形态，如通过扫描电子显微镜所示。对甲醇镁的热分解机理进行了详细的研究。该物质在90、330-350和360-400 °C下分三步分解。通过元素分析（C，H）和红外光谱对两个中间体进行了表征。
The synthesis, structural aspects and thermal behaviour of six different magnesium alcoholates are reported. The magnesium oxides obtained by decomposition of the alkoxides show different particle morphologies, as shown by scanning electron microscopy. The mechanism of the thermal decomposition of magnesium methanolate was studied in detail. The substance decomposed in three steps at 90, 330–350 and 360–400 °C. Two intermediates were characterized by elementary analysis (C, H) and IR spectroscopy.