Synthesis and characterization of a zinc metal–organic framework with chiral nano-pores
Synthesis and characterization of a zinc metal–organic framework with chiral nano-pores
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DOI：
10.1039/c2ce25780g
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发表时间：
2012-07
期刊：
影响因子：
3.1
通讯作者：
Lingjuan Shen;Danielle L. Gray;R. Masel;G. Girolami
中科院分区：
文献类型：
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作者：
Lingjuan Shen;Danielle L. Gray;R. Masel;G. Girolami
Zn3(BPDC)2(O2CH)2·2Et2NCHO是一种新型金属有机骨架，以2,2'-联吡啶-5,5'-二羧酸酯(BPDC)基团作为连接基。虽然这种 MOF 是由非手性组分通过溶剂热合成的，但它具有带有手性纳米孔的三维 (3D) 结构。锌中心通过羧酸盐基团连接在一起形成三核链；两个末端锌原子也与联吡啶基团结合。
Zn3(BPDC)2(O2CH)2·2Et2NCHO is a new metal–organic framework with 2,2′-bipyridine-5,5′-dicarboxylate (BPDC) groups as linkers. Although synthesized solvothermally from achiral components, this MOF has a three dimensional (3D) structure with chiral nano-pores. The zinc centers are linked together by carboxylate groups into trinuclear chains; the two terminal zinc atoms are also bound to bipyridine groups.