New synthetic opportunities using Lewis acidic phosphines

New synthetic opportunities using Lewis acidic phosphines
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使用路易斯酸性膦的新合成机会

DOI:
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发表时间:
2002
期刊:
影响因子:
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通讯作者:
P. Ragogna
P. Ragogna
中科院分区:
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文献类型:
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作者:
N. Burford;P. Ragogna

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膦是过渡金属配合物中传统的刘易斯碱或配体。尽管它们具有富电子(孤对电子)的性质,但刘易斯酸性膦的广泛配位化学正在发展,这突出了导致新结构和键合的新合成方法。
Phosphines are traditional Lewis bases or ligands in transition metal complexes. In spite of their electron-rich (lone pair bearing) nature, an extensive coordination chemistry is developing for Lewis acidic phosphines, which highlights a new synthetic methodology leading to new structure and bonding.