KAURANE AND TRACHYLOBANE DITERPENES FROM XYLOPIA-AETHIOPICA
KAURANE AND TRACHYLOBANE DITERPENES FROM XYLOPIA-AETHIOPICA
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DOI：
10.1016/s0031-9422(00)97022-5
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发表时间：
1994-05-01
期刊：
影响因子：
3.8
通讯作者：
KINGSTON, DGI
中科院分区：
文献类型：
--
作者：
HARRIGAN, GG;BOLZANI, VD;KINGSTON, DGI
通过植物化学研究，分离出了两种新的二萜，15-氧-(-)-三环烷-19-酸和(-)-桃红-15-en-17-al-19-酸。还遇到了已知的化合物15-羟基-(-)-三叶草-19-酸、15-羟基-(-)-鹿皮-16-烯-19-酸（作为不可分离的混合物）、15-氧-(-)-鹿皮-16-烯-19-酸和谷甾醇葡萄糖苷。首次进行了15-羟基-(-)三环烷-19-酸的C-13核磁共振配位及其C-15羟基构型的配位。
Phytochemical investigation of Xylopia aethiopica (Annonaceae) has resulted in the isolation of two novel diterpenes, 15-oxo-(-)-trachyloban-19-oic acid and (-)-kaur-15-en-17-al-19-oic acid. Also encountered were the known compounds 15-hydroxy-(-)-trachyloban-19-oic acid, 15 beta-hydroxy-(-)-kaur-16-en-19-oic acid (as an inseperable mixture), 15-oxo-(-)-kaur-16-en-19-oic acid and sitosterol glucoside. C-13 NMR assignments of 15-hydroxy-(-)trachyloban-19-oic acid and the assignment of the configuration of its hydroxyl group at C-15 have been carried out for the first time.