Synthesis and structure of Cs2Te13 and Cs4Te28, tellurium-rich tellurides on the methanolothermal route to Cs3Te22

Synthesis and structure of Cs2Te13 and Cs4Te28, tellurium-rich tellurides on the methanolothermal route to Cs3Te22
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Cs2Te13 和 Cs4Te28(富碲碲化物)甲醇热法合成 Cs3Te22 的合成和结构

DOI:
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发表时间:
1996
期刊:
影响因子:
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通讯作者:
M. Wachhold
M. Wachhold
中科院分区:
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文献类型:
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作者:
W. Sheldrick;M. Wachhold

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Cs2CO3和As2Te3在160℃和180℃的过热甲醇中反应,分别生成Cs2Te13和Cs4Te28,其阴离子结构包含Te132 -链(Cs2Te13)、Te62 -链和Ten环(n= 4,8)(Cs4Te28)作为构建单元。
Reaction of Cs2CO3 and As2Te3 in superheated methanol at 160 and 180 °C afford Cs2Te13 and Cs4Te28, respectively, whose anionic structures contain Te132– chains (Cs2Te13), Te62– chains and Ten rings (n= 4,8)(Cs4Te28) as building units.