Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex
Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex
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DOI：
10.1021/ic060171q
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发表时间：
2006-04-17
影响因子：
4.6
通讯作者：
Hsu, HF
中科院分区：
文献类型：
--
作者：
Chu, WC;Wu, CC;Hsu, HF
合成并表征了钒（III）硫醇配合物[V（PS3”）（Cl）]- [1a; PS3”= P（C6 H3 -3-（MeSi）-Si-3-2-S）（3）（3-）]和[V（PS3 '）（Cl）]- [1b; PS3' = P（C6 H3 -5-Me-2-S）3（3-）]。络合物Ia用作肼催化还原成氨的前体。光谱和电化学研究表明，肼是结合和激活的V-II状态。
Vanadium(III) thiolate complexes, [V(PS3")(Cl)]- [1a; PS3" = P(C6H3-3-(MeSi)-Si-3-2-S)(3)(3-)] and [V(PS3')(Cl)]- [1b; PS3' = P(C6H3-5-Me-2-S)3(3-)], were synthesized and characterized. Complex la serves as a precursor for the catalytic reduction of hydrazine to ammonia. The spectroscopic and electrochemical studies indicate that hydrazine is bound and activated in a V-II state.