Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate

Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate
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DOI:
10.1039/b417333c
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发表时间:
2005-01-01
影响因子:
4.9
通讯作者:
Leitner, W
Leitner, W
中科院分区:
化学2区
文献类型:
--
作者:
Böing, C;Franciò, G;Leitner, W

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以单齿磷酰胺和威尔克氮磷烯为配体的阳离子镍催化剂对丙二酸二乙基环异构化具有高度的区域选择性和对映选择性。
Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.