Synthesis and structural characterisation of a soluble, metastable indium(I) halide complex, [InBr(tmeda)]
Synthesis and structural characterisation of a soluble, metastable indium(I) halide complex, [InBr(tmeda)]
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DOI：
10.1039/b814658f
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发表时间：
2008-01-01
影响因子：
4.9
通讯作者：
Stasch, Andreas
中科院分区：
文献类型：
--
作者：
Green, Shaun P.;Jones, Cameron;Stasch, Andreas
卤化铟（I）络合物的第一个实例[InBr（tmeda）]已经通过InBr在tmeda-甲苯混合物中的可逆溶解来制备。亚稳化合物的结构表征表明它是单体，具有弱的In。在固体状态下的相互作用。在溶液中，它分解为InBr或[In 2Br 4（tmeda）（2）]。
The first example of an indium(I) halide complex, [InBr(tmeda)], has been prepared by the reversible dissolution of InBr in a tmeda-toluene mixture. The structural characterisation of the metastable compound shows it to be monomeric with weak In ... In interactions in the solid state. In solution, it decomposes to either InBr or [In2Br4(tmeda)(2)].