Neutral metallomacrocycles with four or ten (PEt3)Pd(II) centers.
Neutral metallomacrocycles with four or ten (PEt3)Pd(II) centers.
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DOI:
10.1021/ic048619f
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发表时间:
2005-01
影响因子:
4.6
通讯作者:
Thomas Brasey;R. Scopelliti;K. Severin
中科院分区:
文献类型:
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作者:
Thomas Brasey;R. Scopelliti;K. Severin
The reaction of [(Et(3)P)PdCl(2)](2) with 2,3-dihydroxypyridine, 5-chloro-2,3,-dihydroxypyridine, or 2-hydroxynicotinic acid in the presence of base gives neutral, metallomacrocyclic compounds in which the heterocycles act as dianionic, bridging ligands. The macrocycles contain four or ten palladium atoms as evidenced by single crystal X-ray analyses.