Electronic State of A Hydrogen-Doped Copper Coordination Polymer: N , N ′-bis-(hydroxyethyl)dithiooxamidatocopper(II), (HOC 2 H 4 ) 2 dtoa Cu
Electronic State of A Hydrogen-Doped Copper Coordination Polymer: N , N ′-bis-(hydroxyethyl)dithiooxamidatocopper(II), (HOC 2 H 4 ) 2 dtoa Cu
复制标题
掺氢铜配位聚合物的电子态：N , N -双-(羟乙基)二硫代草酰胺铜(II), (HOC 2 H 4 ) 2 dtoa Cu
DOI：
10.1080/713738609
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发表时间：
2002
影响因子：
0.7
通讯作者：
H. Kitagawa
中科院分区：
文献类型：
--
作者：
M. Fujishima;R. Ikeda;S. Kanda;H. Kitagawa
用电化学方法对标题配位聚合物catena- w - N， N '-双-（羟基乙基）二硫代氨基铜（II）， （HOC 2h 4） 2 dtoa Cu进行了氢掺杂。x射线光电子能谱显示，（HOC 2h4） 2 dtoa Cu中Cu（II）在氢掺杂下氧化态还原为Cu（I，II）混价态。在初始氢掺杂过程中，自旋磁化率增加，但随着氢掺杂的进行，自旋磁化率逐渐减小，并没有温度依赖性。温度无关的行为被认为是由泡利顺磁性推导出来的。配位聚合物氢掺杂自旋磁化率x射线光电子能谱。
Hydrogen doping was electrochemically performed on the title coordination polymer, catena- w - N , N '-bis-(hydroxyethyl)dithiooxamidatocopper(II), (HOC 2 H 4 ) 2 dtoa Cu. From X-ray photoelectron spectroscopy, the oxidation state of Cu(II) in (HOC 2 H 4 ) 2 dtoa Cu was revealed to be reduced to the Cu(I,II) mixed-valence state on hydrogen doping. While the spin susceptibility increases during initial hydrogen doping, it decreases and then shows no temperature dependence as the hydrogen doping proceeds. The temperature-independent behavior is supposed to be derived from Pauli paramagnetism. Coordination polymer Hydrogen doping Spin susceptibility X-ray photoelectron spectroscopy.