Suzuki-Miyaura cross-coupling of benzylic carbonates with arylboronic acids
Suzuki-Miyaura cross-coupling of benzylic carbonates with arylboronic acids
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DOI：
10.1021/ol050078q
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发表时间：
2005-03-03
期刊：
影响因子：
5.2
通讯作者：
Yokogi, M
中科院分区：
文献类型：
--
作者：
Kuwano, R;Yokogi, M
在[Pd(ETA(3)-C3H5)Cl](2)和1，5-二(二苯基膦)戊烷(DPPPent)原位生成的钯催化剂作用下，芳基碳酸酯与芳基硼酸的交叉偶联反应高产率地合成了相应的二芳基甲烷。DPPPent-Pd催化剂上的Suzuki-Miyaura反应适用于合成多种功能化的二芳基甲烷。
The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(eta(3)-C3H5)Cl](2) and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes.