An organogel system can control the stereochemical course of anthracene photodimerization
An organogel system can control the stereochemical course of anthracene photodimerization
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DOI：
10.1039/b820565e
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Shinkai, Seiji
中科院分区：
文献类型：
--
作者：
Dawn, Arnab;Fujita, Norifumi;Shinkai, Seiji
一种新型光响应有机凝胶，具有含有 2-蒽甲酸的二元胶凝剂，显示出高度的立体化学控制，仅产生头对头光环二聚体以及由胶凝剂的手性对应物诱导的显着对映体过量。
A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.