Ultrasmall Pd nanoclusters: facile synthesis and versatile catalytic application
Ultrasmall Pd nanoclusters: facile synthesis and versatile catalytic application
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超小钯纳米团簇：易于合成和多功能催化应用
DOI：
10.1007/s11426-014-5171-2
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发表时间：
2015
影响因子：
9.6
通讯作者：
Zhu Manzhou
中科院分区：
文献类型：
--
作者：
Xiang Ji;Chong Hanbao;Tang Jia;Feng Li;Zhou Bin;Fu Fangyu;Wang Xin;Li Peng;Zhu Manzhou
发展了一种简单有效的制备超小Pd纳米团簇的方法。所得Pd NC显示出均匀的尺寸，平均直径为1.8±0.2 nm。超小Pd纳米粒子和碳纳米管负载的Pd纳米粒子对硝基苯还原和Suzuki偶联反应也表现出优异的催化活性。值得注意的是，反应在温和条件下进行，具有高产率和选择性。
A simple and efficient method for the synthesis of ultrasmall Pd nanoclusters (NCs) has been developed. The as-obtained Pd NCs displayed uniform size with an average diameter of 1.8±0.2 nm. The ultrasmall Pd NCs and carbon nanotubes (CNTs)-supported Pd NCs also showed outstanding catalytic activity for nitrobenzene reduction and Suzuki coupling reactions. Notably, the reactions were conducted under mild conditions with high yield and selectivity.