Mild and efficient removal of hydroxyethyl unit from 2-hydroxyethyl ether derivatives leading to alcohols
Mild and efficient removal of hydroxyethyl unit from 2-hydroxyethyl ether derivatives leading to alcohols
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DOI：
10.1021/ol051135i
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发表时间：
2005-07-21
期刊：
影响因子：
5.2
通讯作者：
Kita, Y
中科院分区：
文献类型：
--
作者：
Fujioka, H;Ohba, Y;Kita, Y
CaN是2-羟乙基醚单元转化为醇的良好试剂。值得注意的是，许多官能团可以耐受反应条件，尽管它们在许多先前报道的去除条件下不能存活。阐明了反应机理。
CAN is a good reagent for the transformation of 2-hydroxyethyl ether units to alcohols. Significantly, many functional groups can tolerate the reaction conditions, although they do not survive under many previously reported removal conditions. The reaction mechanism is clarified.