The isothermal section of the Ag–La–Sn ternary system at 400 °C

The isothermal section of the Ag–La–Sn ternary system at 400 °C
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DOI:
10.1016/j.jallcom.2009.12.087
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发表时间:
2010-03
影响因子:
6.2
通讯作者:
Jianlie Liang;C. Liao;Yong Du;Yi-yuan Tang;Yanmei Han;Yuehui He;Shuhong Liu
Jianlie Liang;C. Liao;Yong Du;Yi-yuan Tang;Yanmei Han;Yuehui He;Shuhong Liu
中科院分区:
材料科学2区
文献类型:
--
作者:
Jianlie Liang;C. Liao;Yong Du;Yi-yuan Tang;Yanmei Han;Yuehui He;Shuhong Liu

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用X射线衍射、扫描电镜和能谱仪测定了Ag-La-Sn三元系在400°C时的相平衡。在该体系中发现了一种新的三元化合物AgLa_5Sn_3。该化合物属于Ti_5Ga_4结构类型,晶胞参数a=0.96827(6),c=0.68747(7)nm。La_2Sn_5为Ce_2Sn_5型结构,a=0.46224(5),B=3.5702(5),c=0.46847(5)nm。
The phase equilibria in the Ag–La–Sn ternary system at 400°C were determined by means of X-ray diffraction, scanning electron microscopy and energy dispersive spectrometer. A new ternary compound AgLa5Sn3was discovered in the system. This compound crystallized in Ti5Ga4structural type with cell parameters of a=0.96827 (6) and c=0.68747 (7)nm. La2Sn5was confirmed to adopt the Ce2Sn5-type structure with a=0.46224 (5), b=3.5702 (5) and c=0.46847 (5)nm.