One-pot synthesis of imines from alcohols and amines with TiO2 loading Pt nanoparticles under UV irradiation.

One-pot synthesis of imines from alcohols and amines with TiO2 loading Pt nanoparticles under UV irradiation.
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DOI:
10.1039/c0cc05615d
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发表时间:
2011-04
影响因子:
4.9
通讯作者:
Yasuhiro Shiraishi;M. Ikeda;D. Tsukamoto;S. Tanaka;T. Hirai
Yasuhiro Shiraishi;M. Ikeda;D. Tsukamoto;S. Tanaka;T. Hirai
中科院分区:
化学2区
文献类型:
--
作者:
Yasuhiro Shiraishi;M. Ikeda;D. Tsukamoto;S. Tanaka;T. Hirai

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TiO(2)负载Pt纳米粒子(Pt@TiO(2))促进了室温下醇和胺的一锅法合成亚胺。这是通过Pt辅助的醇的光催化氧化和所形成的醛与胺在TiO(2)表面上的催化缩合来实现的。
TiO(2) loading Pt nanoparticles (Pt@TiO(2)) promote one-pot synthesis of imines from alcohols and amines under UV irradiation at room temperature. This is achieved via a Pt-assisted photocatalytic oxidation of alcohols and a catalytic condensation of the formed aldehydes with amines on the TiO(2) surface.