Reactivity of three-coordinate iron-NHC complexes towards phenylselenol and lithium phenylselenide.
Reactivity of three-coordinate iron-NHC complexes towards phenylselenol and lithium phenylselenide.
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DOI：
10.1039/c3dt53203h
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发表时间：
2014-02
影响因子：
4
通讯作者：
Thomas Pugh;R. Layfield
中科院分区：
文献类型：
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作者：
Thomas Pugh;R. Layfield
三配位铁（II） NHC配合物[(IPr)Fe(N ")2](1)和[(I(t)Bu)Fe(N ")2] (3) （N " = N(SiMe3)2）与PhSeH或LiSePh反应生成铁（II）硒酸盐[(IPr)Fe(N ")(SePh)](6)和[I(t)Bu(H)][(aI(t)Bu)Fe(SePh)3], [I(t)Bu(H)][7]，配合物7含有异常NHC配体。
The three-coordinate iron(II) NHC complexes [(IPr)Fe(N'')2] (1) and [(I(t)Bu)Fe(N'')2] (3) (N'' = N(SiMe3)2) react with PhSeH or LiSePh to give the iron(II) selenolates [(IPr)Fe(N'')(SePh)] (6) and [I(t)Bu(H)][(aI(t)Bu)Fe(SePh)3], [I(t)Bu(H)][7], with complex 7 containing an abnormal NHC ligand.