Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion
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通过结构导向方法合成具有活性金属位点的 Zn-BTC MOF,以实现高效碳转化

DOI:
10.1039/c3cc49187k
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发表时间:
2014-01-01
影响因子:
4.9
通讯作者:
Wang, Bo
Wang, Bo
中科院分区:
化学2区
文献类型:
--
作者:
Huang, Xianqiang;Chen, Yifa;Wang, Bo

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Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO2 under solvent-and halogen-free conditions without any additives or co-catalysts.